Bummer! I was hoping you'd finally sorted this, since I experienced something similar recently. I haven't had the 'scalded cat' effect yet, but then I still have issues with SAI and fuel mixtures running on LPG.
Your description of your drive to the main road was very interesting as it sounds similar to mine, the only difference being mine is about 3/10 mile long and involves avoiding potholes in the lane.
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2001 A8 D2 FL 3.7 Q - LPG Conversion, Engine: AKC, Gearbox:FBB, Colour:LY5X Aqua Blue pearl effect, Interior:WJ light beige/dark beige valcona leather with burr walnut inserts
My DIY jobs - Replaced alarm horn, Replaced Coolant Temp sensor, Updated RNS-D firmware, Installed Reversing Camera and Digital TV, Dashcam Installation, Retrofitted Rear Blinds, Auto-Dimming Rear View Mirror, Chrome Boot Struts
Sold!  2008 S8 D3 5.2 V10 - Engine: BSM, Gearbox:KLW, Colour:LY7F Suzuka Grey Pearl Effect, Interior:Black/Black with Silver/Black valcona leather with carbon atlas inserts, Bang & Olufsen, Heated windscreen, Soft-close doors, TV, DAB, AMI, Quad Zone, Auto Boot, Auto dim Mirrors, Keyless entry, PDC with rearview camera, AFS II Headlights
My DIY jobs - Fan Jet Windscreen Washers, Retrofitted Electric Side Blinds
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